size and reactivity

Why Are Nanoparticles More Reactive?

Several factors contribute to the enhanced reactivity of nanoparticles:
Surface Atoms: At the nanoscale, a significant fraction of atoms reside on the surface, where they are less tightly bound compared to those in the interior. This makes them more chemically active.
Quantum Effects: Quantum mechanics comes into play at the nanoscale, affecting the electronic states of nanoparticles. These quantum effects can enhance reactivity by altering electronic properties.
Defects and Edges: Nanoparticles often have a high density of defects and edge sites, which are usually more reactive than the smooth surfaces of bulk materials.

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