What Role Do Steric Interactions Play in Self-Assembly?
Self-assembly is a process where molecules spontaneously form well-defined aggregates or structures. Steric interactions are critical in guiding this process at the nanoscale. They influence the final morphology of the assembled structures by dictating how close molecules can pack together. For example, in the formation of micelles or vesicles from amphiphilic molecules, steric hindrance can determine the size and shape of these aggregates.